Invention of biobased polymer alloys and their application in plastic automobile parts

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ABSTRACT Polyamide 11 (PA11), a 100% biobased plastic derived from inedible plants, and polypropylene (PP) were mixed with a reactive compatibilizer using a twin-screw extruder. The


mechanical properties and morphology of the resulting injection-molded PP/PA11 bioalloys were investigated by flexural tests, Charpy notched impact tests, field-emission scanning electron


microscopy (FE-SEM), and transmission electron microscopy (TEM), among other tests. We found that it was possible to control the morphology of the bioalloy and that it had a wide range of


mechanical properties depending on the morphology. When the morphology of the bioalloy was a “ nanosalami” structure, as revealed by FE-SEM, the material had a Charpy notched impact strength


of 70–85 kJ/m2, which is superior to that of polycarbonates, without a large reduction in the flexural modulus. TEM observations showed that the reactive compatibilizers were located in the


interphase between the matrix and dispersed phase. The compatibilizers played a key role in improving impact strength. The bioalloy could be used for foam injection molding; therefore, it


was able to be applied as a foamed door trim, resulting in an approximately 30% weight reduction for the plastic part. Access through your institution Buy or subscribe This is a preview of


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ADDITIONAL ACCESS OPTIONS: * Log in * Learn about institutional subscriptions * Read our FAQs * Contact customer support SIMILAR CONTENT BEING VIEWED BY OTHERS SUSTAINABLE DEVELOPMENT OF


BIOEPOXY COMPOSITES REINFORCED WITH RECYCLED RIGID POLYURETHANE FOAM FOR MECHANICAL, THERMAL, ACOUSTIC, AND ELECTROMAGNETIC APPLICATIONS IN A CIRCULAR ECONOMY APPROACH Article Open access 10


March 2025 PERFORMANCE OF GLASS FIBER REINFORCED POLYAMIDE COMPOSITES EXPOSED TO BIOETHANOL FUEL AT HIGH TEMPERATURE Article Open access 19 August 2022 PENTADECAFLUOROOCTANOIC-ACID-FREE


POLYTETRAFLUOROETHYLENE AND MECHANISM OF PFOA FORMATION BY Γ-IRRADIATION Article Open access 18 August 2020 REFERENCES * MacArthur E. Beyond plastic waste. Science 2017;358:843. Article  CAS


  PubMed  Google Scholar  * https://www.undp.org/united-states/sustainable-development-goals. Accessed 31 Aug 2022. *


https://global.toyota/en/sustainability/esg/challenge2050/?_ga=2.54814819.95233906.1661070302-695201248.1658734777. Accessed 31 Aug 2022. * Lim LT, Auras R, Rubino M. Processing technologies


for poly(lactic acid). Prog Polym Sci. 2008;33:820–2. Article  CAS  Google Scholar  * Nampoothiri KM, Nair NR, John RP. An overview of the recent developments in polylactide (PLA) research.


Bioresour Technol. 2010;101:8493–501. Article  Google Scholar  * Lenz RW, Marchessault RH. Bacterial polyesters: Biosynthesis, biodegradable plastics and biotechnology. Biomacromolecules


2005;6:1–8. Article  CAS  PubMed  Google Scholar  * Iwata T. Biodegradable and bio-based polymers: Future prospects of eco-friendly plastics. Angew Chem Int Ed. 2015;54:3210–5. Article  CAS


  Google Scholar  * Lütke-Eversloh T, Fischer A, Remminghorst U, Kawada J, Marchessault RH, Boögershausen A, et al. Biosynthesis of novel thermoplastic polythioesters by engineered


Escherichia coli. Nat Mater. 2002;1:236–40. Article  PubMed  Google Scholar  * Sano H, Usami T, Nakagawa H. Lamellar morphologies of melt-crystallized polyethylene, isotactic polypropylene


and ethylene-propylene copolymers by the Ru04 staining technique. Polymer 1986;27:1497–504. Article  CAS  Google Scholar  * Kawada J, Kitou M, Mouri M, Mitsuoka T, Araki T, Lee CH, et al.


Morphology controlled PA11 bio-alloys with excellent impact strength. ACS Sustain. Chem Eng. 2016;4:2158–64. CAS  Google Scholar  * Donald AM, Kramer EJ. Craze initiation and growth in


high-impact polystyrene. J Appl Polym Sci. 1982;27:3729–41. Article  CAS  Google Scholar  * Fischer M, Hellmann GP. On the evolution of phase patterns during the high-impact-modified


polystyrene process. Macromolecules 1996;29:2498–509. Article  CAS  Google Scholar  * Kawada J, Kitou M, Mouri M, Kato Y, Katagiri Y, Matsushita M, et al. Super impact absorbing bio-alloys


from inedible plants. Green Chem. 2017;19:4503–8. Article  CAS  Google Scholar  * Ide F, Hasegawa A. Studies on polymer blend of nylon 6 and polypropylene or nylon 6 and polystyrene using


the reaction polymer. J Appl Polym Sci. 1974;18:963–74. Article  CAS  Google Scholar  * Gupta AK, Purwar SN. Crystallization of PP in PP/SEBS blends and its correlation with tensile


properties. J Appl Polym Sci. 1984;29:1595–609. Article  CAS  Google Scholar  * Wu S. Phase structure and adhesion in polymer blends: A criterion for rubber toughening. Polymer


1985;26:1855–63. Article  CAS  Google Scholar  * Wu S. A generalized criterion for rubber toughening: The critical matrix ligament thickness. J Appl Polym Sci. 1988;35:549–61. Article  CAS 


Google Scholar  * Wu S. Chain structure, phase morphology, and toughness relationships in polymers and blends. Polym Eng Sci. 1990;30:753–61. Article  CAS  Google Scholar  * Muratoglu OK,


Argon AS, Cohen RE, Weinberg M. Toughening mechanism of rubber-modified polyamides. Polymer 1995;36:921–30. Article  CAS  Google Scholar  *


https://www.chemistryworld.com/news/castable-polymers-made-from-castor-beans/3007982.article. Accessed 31 Aug 2022. * https://www.toyota-boshoku.com/global/news/6783.html. Accessed 31 Aug


2022. Download references ACKNOWLEDGEMENTS The authors are grateful to Dr. Arimitsu Usuki and Mr. Osamu Kitou for their enormous guidance, strong encouragement, and continuous support.


AUTHOR INFORMATION AUTHORS AND AFFILIATIONS * Toyota Central R&D laboratories, Inc., 41-1 Yokomichi, Nagakute, Aichi, 480-1192, Japan Jumpei Kawada & Makoto Mouri * Toyota Boshoku


Corporation, 88 Kanayama, Kamekubi, Toyota, Aichi, 470-0395, Japan Masayuki Kitou, Toshiyuki Ario & Keisuke Kato Authors * Jumpei Kawada View author publications You can also search for


this author inPubMed Google Scholar * Masayuki Kitou View author publications You can also search for this author inPubMed Google Scholar * Makoto Mouri View author publications You can also


search for this author inPubMed Google Scholar * Toshiyuki Ario View author publications You can also search for this author inPubMed Google Scholar * Keisuke Kato View author publications


You can also search for this author inPubMed Google Scholar CORRESPONDING AUTHOR Correspondence to Jumpei Kawada. ETHICS DECLARATIONS CONFLICT OF INTEREST The authors declare no competing


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ARTICLE CITE THIS ARTICLE Kawada, J., Kitou, M., Mouri, M. _et al._ Invention of biobased polymer alloys and their application in plastic automobile parts. _Polym J_ 55, 753–760 (2023).


https://doi.org/10.1038/s41428-023-00760-1 Download citation * Received: 21 September 2022 * Revised: 09 January 2023 * Accepted: 11 January 2023 * Published: 16 March 2023 * Issue Date:


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