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Despite over a century of research to understand heterogeneous electrocatalysis, the precise mechanisms of action remain poorly understood. Now, it is proposed that the oxygen evolution
reaction on IrO_x_ is driven by changes in the redox state of the Ir–O active sites, rather than by changes in the interfacial electric field. Access through your institution Buy or
subscribe This is a preview of subscription content, access via your institution RELEVANT ARTICLES Open Access articles citing this article. * OXIDATION OF INTERFACIAL COBALT CONTROLS THE PH
DEPENDENCE OF THE OXYGEN EVOLUTION REACTION * Jinzhen Huang * , Adam H. Clark * … Emiliana Fabbri _Nature Chemistry_ Open Access 28 March 2025 * BIFUNCTIONAL MIXED-VALENCE RUTHENIUM
HETEROSTRUCTURE FOR ROBUST ELECTROCATALYTIC WATER SPLITTING IN ACID MEDIA * Xinyu Xie * , Yixiao Zhang * … Peng Du _Advanced Composites and Hybrid Materials_ Open Access 18 January 2025 *
MOLECULAR-SCALE INSIGHTS INTO THE ELECTRICAL DOUBLE LAYER AT OXIDE-ELECTROLYTE INTERFACES * Chunyi Zhang * , Marcos F. Calegari Andrade * … Annabella Selloni _Nature Communications_ Open
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about institutional subscriptions * Read our FAQs * Contact customer support REFERENCES * Guidelli, R. et al. _Pure Appl. Chem._ 86, 245–258 (2014). Article CAS Google Scholar *
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CAS Google Scholar * Warburton, R. E. et al. _J. Am. Chem. Soc._ 142, 20855–20864 (2020). Article CAS Google Scholar Download references AUTHOR INFORMATION AUTHORS AND AFFILIATIONS *
The Department of Chemistry and Biochemistry and the Oregon Center for Electrochemistry, University of Oregon, Eugene, OR, USA Shannon W. Boettcher * The Department of Chemistry,
Massachusetts Institute of Technology, Cambridge, MA, USA Yogesh Surendranath * Center for Interfacial Ionics, Eugene, OR, USA Shannon W. Boettcher & Yogesh Surendranath Authors *
Shannon W. Boettcher View author publications You can also search for this author inPubMed Google Scholar * Yogesh Surendranath View author publications You can also search for this author
inPubMed Google Scholar CORRESPONDING AUTHORS Correspondence to Shannon W. Boettcher or Yogesh Surendranath. ETHICS DECLARATIONS COMPETING INTERESTS The authors declare no competing
interests. RIGHTS AND PERMISSIONS Reprints and permissions ABOUT THIS ARTICLE CITE THIS ARTICLE Boettcher, S.W., Surendranath, Y. Heterogeneous electrocatalysis goes chemical. _Nat Catal_ 4,
4–5 (2021). https://doi.org/10.1038/s41929-020-00570-1 Download citation * Published: 06 January 2021 * Issue Date: January 2021 * DOI: https://doi.org/10.1038/s41929-020-00570-1 SHARE THIS
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