Crystallization of Poly(ε-caprolactone)-block-Polystyrene Copolymers from Glassy Microdomain Structures


Play all audios:

Loading...

Download PDF Note Published: 01 January 2000 Crystallization of Poly(ε-caprolactone)-block-Polystyrene Copolymers from Glassy Microdomain Structures Shuichi Nojima1, Hiroshi Kakihira1,


Satoshi Tanimoto1, Hisayuki Nakatani2 & …Shintaro Sasaki1 Show authors Polymer Journal volume 32, pages 75–78 (2000)Cite this article


612 Accesses


11 Citations


Metrics details


Article PDF References I. W. Hamley, “The Physics of Block Copolymers,” Oxford University Press, Oxford 1998.


Google Scholar 


J. J. Herman, R. Jerome, P. Teyssie, M. Gervais, and B. Gallot, Makromol. Chem., 182, 997 (1981).


J. Heuschen, R. Jerome, and P. Teyssie, J. Polym. Sci., B27, 523 (1989).


L. Liu, H. Li, B. Jiang, and E. Zhou, Polymer, 35, 5511 (1994).


L. Liu, B. Jiang, and E. Zhou, Polymer, 37, 3937 (1996).


V. Balsamo, F. Gyldenfeldt, and R. Stadler, Macromol. Chem. Phys., 197, 3317 (1996).


L. Liu, F. Yeh, and B. Chu, Macromolecules, 29, 5336 (1996).


S. Nojima, H. Tanaka, A. Rohadi, and S. Sasaki, Polymer, 39, 1727 (1998).


S. Nojima, M. Fujimoto, H. Kakihira, and S. Sasaki, Polym. J., 30, 968 (1998).


F. S. Bates and G. H. Fredrickson, Annu. Rev. Phys. Chem., 41, 525 (1990).


T. Shiomi, H. Tsukada, H. Yoshise, K. Takenaka, and Y. Tezuka, Polym. Prepr., Jpn., 46, 808 (1997).


M. Gervais and B. Gallot, Polymer, 22, 1129 (1981).


F. B. Khambatta, F. Warner, T. Russell, and R. S. Stein, J. Polym. Sci., Polym. Phys. Ed., 14, 1391 (1976).


S. Nojima, K. Hashizume, A. Rohadi, and S. Sasaki, Polymer, 38, 2711 (1997).


S. Nojima, M. Kuroda, and S. Sasaki, Polym. J., 29, 642 (1997).


V. Crescenzi, G. Manzini, G. Galzolari, and C. Borri, Eur. Polym. J., 8, 449 (1972).


M. J. Richardson and N. G. Savil, Polymer, 18, 3 (1977).


K. Ito and Y. Yamashita, Macromolecules, 11, 68 (1978).


A. K. Khandpur, C. W. Macosko, and F. S. Bates, J. Polym. Sci., B33, 247 (1995).


Precisely, the plot of D vs. φPVC1/2 is necessary to obtain D0 for CL7022 because the microdomain structure is a hexagonally packed cylinder. However, we used the D vs. φPVC plot to evaluate


D0 because of small φPVC.


D. J. Quiram, R. A. Register, and G. R. Marchand, Macromolecules, 30, 4551 (1997).


H. Tanaka, H. Hasegawa, and T. Hashimoto, Macromolecules, 24, 240 (1991).


Download references


Author informationAuthors and Affiliations School of Materials Science, Japan Advanced Institute of Science and Technology (JAIST), Tatsunokuchi, Ishikawa, 923-1292, Japan


Shuichi Nojima, Hiroshi Kakihira, Satoshi Tanimoto & Shintaro Sasaki


Center for New Materials, Japan Advanced Institute of Science and Technology (JAIST), Tatsunokuchi, Ishikawa, 923-1292, Japan


Hisayuki Nakatani


AuthorsShuichi NojimaView author publications You can also search for this author inPubMed Google Scholar


Hiroshi KakihiraView author publications You can also search for this author inPubMed Google Scholar


Satoshi TanimotoView author publications You can also search for this author inPubMed Google Scholar


Hisayuki NakataniView author publications You can also search for this author inPubMed Google Scholar


Shintaro SasakiView author publications You can also search for this author inPubMed Google Scholar


Rights and permissions Reprints and permissions


About this articleCite this article Nojima, S., Kakihira, H., Tanimoto, S. et al. Crystallization of Poly(ε-caprolactone)-block-Polystyrene Copolymers from Glassy Microdomain Structures.


Polym J 32, 75–78 (2000). https://doi.org/10.1295/polymj.32.75


Download citation


Issue Date: 01 January 2000


DOI: https://doi.org/10.1295/polymj.32.75


Share this article Anyone you share the following link with will be able to read this content:


Get shareable link Sorry, a shareable link is not currently available for this article.


Copy to clipboard Provided by the Springer Nature SharedIt content-sharing initiative


KeywordsCrystalline-Amorphous Diblock CopolymerMicrodomain StructureGlass TransitionCrystallization