Studies on the polymerization of acrolein oxime. Xiii. Initial processes of the radiation-induced polymerization


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ABSTRACT The radiation-induced polymerization of acrolein oxime was carried out at temperatures ranging from room temperature to −78°C, and the resulting low molecular products were analyzed


by gas chromatography-mass spectrometry. Acetaldoxime, propionaldoxime, propenylhydroxylamines, dioximes etc. were obtained. Initial processes of the polymerization are discussed on the


basis of these reaction products. The present work offers further corroborating evidence for the already-described postulation that an anionic mechanism is operative above room temperature,


and a cationic mechanism is predominant below −23°C. SIMILAR CONTENT BEING VIEWED BY OTHERS AUTOPOLYMERIZATION OF 2-BROMO-3-METHOXYTHIOPHENE, ANALYSIS OF REACTION PRODUCTS AND ESTIMATION OF


POLYMER STRUCTURE Article 27 October 2020 THEORETICAL INVESTIGATION OF THE MECHANISM, KINETICS AND SUBSEQUENT DEGRADATION PRODUCTS OF THE NO3 RADICAL INITIATED OXIDATION OF ACROLEIN Article


Open access 21 February 2025 SILYLOXY-SUBSTITUTED ANTHRAQUINONES AS TYPE I PHOTOINITIATORS FOR VISIBLE LIGHT-INDUCED RADICAL POLYMERIZATION Article Open access 07 January 2025 ARTICLE PDF


REFERENCES * S. Masuda, H. Tamai, M. Torii, M. Tanaka, and T. Ota, _Polym. J._, 11, 213 (1979). * S. Masuda, H. Kihara, and T. Ota, _Nippon Kagaku Kaishi_, 608 (1974). * S. Masuda, M.


Tanaka, and T. Ota, _Polym. J._, 10, 387 (1978). * S. Masuda and T. Ota, _Polym. J._, 9, 459 (1977). * S. Masuda and T. Ota, _Polym. J._, 9, 465 (1977). * S. Masuda and T. Ota, _Polym. J._,


10, 397 (1978). * S. Masuda and T. Ota, _Kobunshi Ronbunshu_, 31, 61 (1974). Download references AUTHOR INFORMATION AUTHORS AND AFFILIATIONS * Department of Applied Chemistry, Faculty of


Engineering, Tokushima University, Tadatoshi Ota, Yoshikazu Mori, Harumi Tamai & Seizo Masuda * Faculty of Pharmaceutical Science, Tokushima University of Arts and Science, Masami Tanaka


Authors * Tadatoshi Ota View author publications You can also search for this author inPubMed Google Scholar * Yoshikazu Mori View author publications You can also search for this author


inPubMed Google Scholar * Masami Tanaka View author publications You can also search for this author inPubMed Google Scholar * Harumi Tamai View author publications You can also search for


this author inPubMed Google Scholar * Seizo Masuda View author publications You can also search for this author inPubMed Google Scholar RIGHTS AND PERMISSIONS Reprints and permissions ABOUT


THIS ARTICLE CITE THIS ARTICLE Ota, T., Mori, Y., Tanaka, M. _et al._ Studies on the Polymerization of Acrolein Oxime. XIII. Initial Processes of the Radiation-Induced Polymerization. _Polym


J_ 12, 687–694 (1980). https://doi.org/10.1295/polymj.12.687 Download citation * Issue Date: 01 October 1980 * DOI: https://doi.org/10.1295/polymj.12.687 SHARE THIS ARTICLE Anyone you share


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Nature SharedIt content-sharing initiative KEYWORDS * Acrolein Oxime * O-Substituted Acrolein Oximes * N-Substituted Hydroxylamines * Dioximes * Radiation-Induced Polymerization * Gas


Chromatography-Mass Spectrometry Analysis