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The performance of photogalvanic cells for the direct conversion of solar energy to electrical energy depends on the cell photochemistry, the homogeneous kinetics, the mass transport, the
electrode kinetics and the load on the cell. The variation of the power output with the concentrations of the redox couples, their transport and kinetic parameters and the dimensions of the
cell is found. The power conversion efficiency of the optimal cell could be as large as 18% but it is unlikely that all the necessary conditions can be met. A more realistic estimate of the
maximum power conversion efficiency that could be achieved from a photogalvanic cell is between 5 and 9%.
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