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ABSTRACT IT was recently found in this laboratory1 that the symmetry of _cyclo_pentadienyl nickel nitrosyl is simply and unequivocally shown by its microwave spectrum. We have now applied
the same method to demonstrate the symmetries of _cyclo_pentadienyl thallium, _cyclo_pentadienyl manganese tricarbonyl and benzene chromium tricarbonyl. The manganese compound had sufficient
vapour pressure at room temperature, but the other materials were studied in a Stark modulation spectrometer operated at about 100° C. You have full access to this article via your
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ARTICLE PDF REFERENCES * Cox, A. P., Thomas, L. F., and Sheridan, J., _Nature_, 181, 1157 (1958). Article ADS CAS Google Scholar * Cotton, F. A., and Reynolds, L. T., _J. Amer. Chem.
Soc._, 80, 269 (1958). Article CAS Google Scholar * Dunitz, J. D., Orgel, L. E., and Rich, A., _Acta Cryst._, 9, 373 (1956). Article CAS Google Scholar * _“Interatomic Distances”_,
Chemical Society, London, Special Pub. No. 11 (1958). * Honig, A., Mandel, M., Stitch, M. L., and Townes, C. H., _Phys. Rev._, 96, 629 (1954). Article ADS CAS Google Scholar * Barrett,
A. H., and Mandel, M., _Phys. Rev._, 109, 1572 (1958). Article ADS CAS Google Scholar Download references AUTHOR INFORMATION AUTHORS AND AFFILIATIONS * Department of Chemistry, The
University, Birmingham, 15 J. K. TYLER, A. P. COX & J. SHERIDAN Authors * J. K. TYLER View author publications You can also search for this author inPubMed Google Scholar * A. P. COX
View author publications You can also search for this author inPubMed Google Scholar * J. SHERIDAN View author publications You can also search for this author inPubMed Google Scholar RIGHTS
AND PERMISSIONS Reprints and permissions ABOUT THIS ARTICLE CITE THIS ARTICLE TYLER, J., COX, A. & SHERIDAN, J. Molecular Symmetry in _Cyclo_pentadienyl Thallium and Some Related
Substances from their Microwave Spectra. _Nature_ 183, 1182–1183 (1959). https://doi.org/10.1038/1831182a0 Download citation * Issue Date: 25 April 1959 * DOI:
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